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Theses/Dissertations
Author Hessley, Rita K. (Rita Kathleen), author.

Title The oxidative decarboxylation of aminopolycarboxylic acids with cerium (IV) in sulfuric acid / by Rita Kathleen Hessley, 1946-.

Published Rolla, Missouri : University of Missouri--Rolla, [1971]
LOCATION CALL # STATUS
 MST DEPOSITORY  THESIS T 2554 c.2  NOT CHECKED OUT
 MST DEPOSITORY  THESIS T 2534/2563  MICROFILM    NOT CHECKED OUT
 MST DEPOSITORY  THESIS T 2534/2563  MICROFILM    NOT CHECKED OUT
 MST Thesis  THESIS T 2554    NOT CHECKED OUT
Description vii, 46, 20 appendix leaves : illustrations ; 29 cm
Summary "The rates of oxidation of four chelating agents, NTA, EDTA CDTA, and DTPA with Ce(IV), in sulfuric acid media, were determined spectrophotometrically by a stopped-flow technique. The reductive ability is in the order CDTA>EDTA>DTPA>NTA. The influence of varying the acidity of the medium was studied, and in each case a maximum in the rate constant [H +] plot was observed. A possible interpretation of the reactivities and the influence of acidity is advanced"--Summary, leaf 1.
Notes "This paper consists of three papers prepared for publication"--Leaf ii.
Vita.
Typescript.
M.S. University of Missouri--Rolla 1971.
Includes bibliographical references.
Subjects Complexometric titration.
Transition metals.
Cerium group.
Other Titles The Oxidative Decarboxylation of Polyaminocarboxylic Acids.
A kinetic study of the complex formation and oxidation of diethylenetriaminepentaacetic acid (DTPA) with cerium(IV) in sulfuric acid media.
The oxidative decarboxylation of polyaminocarboxylic acids-III. A study of the reaction of diethylenetriaminepentaacetic acid (DTPA) with cerium (IV) in sulfuric acid media.
MST Thesis. Chemistry (M.S., 1971)
OCLC/WorldCat Number 6034141
Permanent Link
http://merlin.lib.umsystem.edu:80/record=b1066531~S5