Theses/Dissertations
Author Smith, Alan Wayne, 1946- author.

Title Liquid-liquid extraction with first order reaction : a mathematical simulation / by Alan Wayne Smith.

Published [Rolla, Missouri] : University of Missouri--Rolla, [1973]
LOCATION CALL # STATUS
 MST DEPOSITORY  THESIS T 2840/2866  MICROFILM    NOT CHECKED OUT
 MST Thesis  THESIS T 2860    NOT CHECKED OUT
Description xi, 50 leaves : illustrations ; 29 cm
Summary "Models for mass transfer to droplets based on film theory with first order chemical reaction are proposed and compared with experimental data. The experimental extraction data is available from the work by Andoe (1968). The physical system used was benzene as a continuous phase and water as a dispersed phase with 2-chloro-2- methyl propane the solute diffusing into and reacting in the droplet. This system had a high interfacial tension (31.0 dynes/cm) and droplet Reynolds numbers ranging from 600 to 1345. The predicted results of this work are in the form of the dimensionless total mass transferred to the droplet vs dimensionless contact time. These predictions are compared with the dimensionless experimental data presented by Andoe with corrections for end effects. The non-oscillating drop model developed here deviated from the experimental data by an Average Absolute Percent Deviation (AAPD) of about 78.6%. The cause of this wide deviation is suspected to be related to the use in this model of the Skelland and Wellek (1964). Sherwood number correlation, which was developed from low interfacial tension systems (a < 5 dynes/cm). Future work will be necessary to reduce this large deviation. The oscillating drop model compared more favorably with experimental data, the AAPD being about 14 .4%. The Sherwood number correlation for mass transfer without reaction which was used in the developed model, was previously found to be applicable to both low and high interfacial tension systems by Brunson and Wellek (1970)"--Abstract, leaf ii.
Notes Vita.
Typescript.
M.S. University of Missouri--Rolla 1973.
Includes bibliographical references (leaves 26-27).
Subjects Mass transfer -- Mathematical models.
Extraction (Chemistry)
Drops.
Other Titles MST Thesis. Chemical Engineering (M.S., 1973)
OCLC/WorldCat Number 6028934
Author Smith, Alan Wayne, 1946- author.
Title Liquid-liquid extraction with first order reaction : a mathematical simulation / by Alan Wayne Smith.
Subjects Mass transfer -- Mathematical models.
Extraction (Chemistry)
Drops.
Other Titles MST Thesis. Chemical Engineering (M.S., 1973)