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Author Gujarathi, Ramesh Natwarlal, 1941- author.

Title Decarboxylation of malonic acid in aqueous solutions / by Ramesh Natwarlal Gujarathi.

Published Rolla, Missouri : University of Missouri at Rolla, [1966]
LOCATION CALL # STATUS
 MST DEPOSITORY  THESIS T 1859 c.2  NOT CHECKED OUT
 MST Thesis  THESIS T 1859    NOT CHECKED OUT
Description viii, 96 leaves : illustrations ; 28 cm
Summary "The rate of decarboxylation of malonic acid in aqueous solutions was studied over a range of concentrations, pH's, and temperatures. The catalytic effect of various divalent metallic ions was also studied at a pH of 0.3. these studies did not support a truly unimolecular decomposition as the experimental order was found to be slightly greater than one. An empirical relation for the rate of decarboxylation was formulated in which the undissociated malonic acid and the monovalent malonate ion were the reactive species. A possible mechanism of decarboxylation due to solvent activation was postulated. No pronounced catalytic effect due to the divalent metal ions was observed"--Abstract, leaf ii.
Notes M.S. University of Missouri at Rolla 1966
Vita.
Includes bibliographical references (leaves 93-94).
Subjects Malonic acid.
Decarboxylation.
Solution (Chemistry)
Other Titles MST Thesis. Chemical Engineering (M.S., 1966)
Additional Keywords Decarboxylation.
Malonic acid.
Solution (Chemistry)
OCLC/WorldCat Number 5973295
Author Gujarathi, Ramesh Natwarlal, 1941- author.
Title Decarboxylation of malonic acid in aqueous solutions / by Ramesh Natwarlal Gujarathi.
Subjects Malonic acid.
Decarboxylation.
Solution (Chemistry)
Additional Keywords Decarboxylation.
Malonic acid.
Solution (Chemistry)
Other Titles MST Thesis. Chemical Engineering (M.S., 1966)
Permanent Link
http://merlin.lib.umsystem.edu:80/record=b1068556~S5