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Theses/Dissertations
Author Sheth, Ramesh Nagindas, 1939- author.

Title The kinetics of the reaction of m-nitrobenzyl bromide with hydroxide ion in aqueous-aprotic solvent mixtures / by Ramesh Nagindas Sheth.

Published Rolla, Missouri : University of Missouri at Rolla, [1966]
LOCATION CALL # STATUS
 MST DEPOSITORY  THESIS T 1843 c.2  NOT CHECKED OUT
 MST Thesis  THESIS T 1843    NOT CHECKED OUT
Description v, 53 leaves, 2 figures : illustrations ; 28 cm
Summary "The reaction between m-nitrobenzyl bromide and sodium hydroxide in homogeneous aqueous dioxane and aqueous tetrahydrofuran media was studied. The product of the reaction was identified by infra red, gas chromatography and chemical tests as m-nitrobenzyl alcohol. The kinetics of the reaction are second order with practically no variation in the rate constants as the % of the organic solvent was changed in the medium. This seems to imply hydrolysis of the organic halide by a process involving both bond-breaking and bond-formation in the transition state. The activation energy, measured in 50% aqueous dioxane, between 20° and 69.5°C at 5 different temperatures, is 15,500 cal/mole"--Abstract, leaf i.
Notes M.S. University of Missouri at Rolla 1966
Vita.
Typescript.
Subjects Chemical kinetics.
Organic solvents.
Other Titles MST Thesis. Chemical Engineering (M.S., 1966)
Additional Keywords Chemical kinetics.
Organic solvents.
OCLC/WorldCat Number 5972979
Author Sheth, Ramesh Nagindas, 1939- author.
Title The kinetics of the reaction of m-nitrobenzyl bromide with hydroxide ion in aqueous-aprotic solvent mixtures / by Ramesh Nagindas Sheth.
Subjects Chemical kinetics.
Organic solvents.
Additional Keywords Chemical kinetics.
Organic solvents.
Other Titles MST Thesis. Chemical Engineering (M.S., 1966)
Permanent Link
http://merlin.lib.umsystem.edu:80/record=b1068587~S5